Don't worry, we'll figure it out
Those options in Export PNG dialog are for choosing which portion of the file you want to export. You can export just what is selected, or just what's in the page borders, or the whole drawing no matter about the page border, or some custom area. They probably don't have anything to do with this white background issue.
And you didn't import anything? Didn't click Edit menu > Make a Bitmap Copy? Is there any chance there might be a big white object (rectangle or circle or something) that you forgot was there? If it doesn't have a stroke, and you haven't changed Inkscape's background, it's effectively invisible.
Can you share a sample SVG file with a problematic object or drawing, so we can investigate or test with it?