I'm not sure if I misunderstand your questions, or if you possibly have a misunderstanding about Inskcape's abilities.
Are you using this extension?
http://wiki.inkscape.org/wiki/index.php/ExportPDFCMYK Or some other technique to produce CMYK color model, such as using Scribus?
http://libregraphicsworld.org/blog/entry/getting-cmyk-colors-from-inkscape-to-scribusInkscape doesn't have any native,
true CMYK ability. Even though in the Fill and Stroke dialg, there's a type of color called CMYK, it's not the true color print model. I never have understood exactly what it is. I guess it's just a different way use color.
The effect you're seeing where you set specific values for R, G, or B or C, M, Y, or K, and other values change automatically, is seen with all of Inkscape's color controls. I'm not very knowledgeable about the technical aspects of color, and I don't know if that's a bug, or expected behavior. In general, and in my opinion, printing is not one of Inkscape's strong points.
There is a way to set up Inkscape to use the same color profile as your monitor.....I think I said that right
Anyway, have a look at Inkscape Preferences > Input/Output > Color Management. Maybe that will get you closer to your goal?
Or if you do need true CMYK print color, you could try the PDF/CMYK Export extension, or use Scribus and the tutorial, both linked above.
And of course, we can always consult the manual:
http://tavmjong.free.fr/INKSCAPE/MANUAL/html/Attributes-Fill-Stroke.html#Attributes-Colorand possibly the Tweak tool could help you
http://tavmjong.free.fr/INKSCAPE/MANUAL/html/Tweak-Colors.htmlLet me know if I've misunderstood, and I'll try again. Or maybe one of our other members will have the answer