Thank you, Moini and brynn. I tried Moini's method. In my hands, the spectrum looks fine now, but the axes became a mess. I need to practice to do it right, I think. Also, it seems to require a lot of computer resources to get deep ungroup done with even this simple graph.
brynn made a very good point about raster graphics. I always thought NMR spectra as line drawings, and my previous postscript files have always been vector graphics. Perhaps this is really raster graphics. The goal of my using Inkscape is to get at the objects. For example, I can select objects from several different spectra plots (if I plot them with same dimensions), and align them properly, just keep one axis frame to cover them all, and adjust linewidths if it helps the clarity. This is useful to compare data from different samples. To some extent it can be done with the TopSpin software, but the plots have other limitations. It is not obvious that you can do this with GIMP. One factor of deterring me using GIMP more is the fact I have not figured out how to do annotation wit it. Inkscape is much more intuitive to me.
I have worked out a way to mixed use of GIMP and Inkscape. I think Moini's method of deep ungroup may be useful for me to treat data obtained from another manufacturer's instrument. Thank you.